Portable catalytic heater

ABSTRACT

Provided is a portable heating device comprising a combustion-powered heater, a regulator, and an oxygen depletion sensor. The combustion-powered heater may be supplied by an associated fuel source and may comprise a combustion region comprising a catalytic surface. The regulator may be adapted for fluid communication with the associated fuel source. The oxygen depletion sensor may comprise a burner and a temperature detector. The burner may be in fluid communication with the regulator and may be adapted to combust fuel form the regulator with air to produce a flame. The temperature detector may be adapted to detect the temperature of the flame and may be adapted to selectively render the combustion-powered heater non-functional.

TECHNICAL FIELD

Provided is a portable catalytic heater. More particularly, provided isportable catalytic heater comprising a device to shut down the portablecatalytic heater in response to certain atmospheric conditions.

BACKGROUND

Without limitation, combustion-powered heaters may comprise catalyticheaters and heaters with burners. Combustion-powered heaters combustreactants to yield heat and reaction products. Combustion-poweredheaters consume a fuel and an oxidant and react the fuel and oxidant toyield heat and one or more combustion products. Some combustion-poweredheaters modify the composition of the atmosphere by uptake of one ormore reactants from the atmosphere, or release of one or more combustionproducts into the atmosphere, or both.

In some combustion-powered heaters, a combustion process consumes oxygenfrom the atmosphere as a combustion reactant. The consumption of oxygenby a combustion-powered heater can modify the composition of theatmosphere by reducing the oxygen therein. In some amounts, reducedoxygen may be undesirable. It remains desirable to develop technology todetect and address atmospheric conditions such as undesirable amounts ofoxygen.

Without limitation, some combustion-powered heaters release a combustionproduct into the atmosphere. A combustion product may comprise, but isnot limited to, carbon dioxide, carbon monoxide, nitrogen oxides. Therelease of a combustion product can modify the composition of theatmosphere by increasing the amount of a combustion product therein.Without limitation, increasing the amount of a combustion product in theatmosphere can decrease the percentage of other atmospheric constituentstherein. Without limitation, in some amounts, the presence of acombustion product may be undesirable. It remains desirable to developtechnology to detect and address atmospheric conditions such as anundesirable amount of a combustion product in the atmosphere.

SUMMARY

Provided is a portable heating device comprising a combustion-poweredheater, a regulator, and an oxygen depletion sensor. Thecombustion-powered heater may be supplied by an associated fuel sourceand may comprise a combustion region comprising a catalytic surface. Theregulator may be adapted for fluid communication with the associatedfuel source. The oxygen depletion sensor may comprise a burner and atemperature detector. The burner may be in fluid communication with theregulator and may be adapted to combust fuel form the regulator with airto produce a flame. The temperature detector may be adapted to detectthe temperature of the flame and may be adapted to selectively renderthe combustion-powered heater non-functional.

Further provided is a portable combustion-powered heater supplied by anassociated fuel source. The combustion-powered heater may comprise acombustion region comprising a catalytic surface, a regulatoroperationally engaged with the associated fuel source, a valve, and anoxygen depletion sensor operationally engaged with the regulator. Theoxygen depletion sensor may comprise, a burner in operative engagementwith said regulator and a detector. The burner may be adapted to combustfuel in air to produce a flame. The detector may be adapted to detect afirst property of the flame.

Further provided is a portable heating device comprising acombustion-powered heater, a regulator, a normally-closed valve, and anoxygen depletion sensor. The combustion-powered heater may be suppliedby an associated fuel source. The fuel source may comprise propane. Thecombustion-powered heater may comprise a combustion region. Thecombustion region may comprise a catalyst and a substrate. The catalystmay comprise ruthenium, rhodium, palladium, osmium, iridium, platinum,or mixtures thereof. The substrate may comprise a glass fiber, a porousmetal, a ceramic, or a mixture thereof. The combustion-powered heatermay be adapted to consume oxygen from the atmosphere as a combustionreactant or adapted to release a combustion product into the atmosphere,or both. The regulator may be operationally engaged with the associatedfuel source. The regulator may be adapted to accept a flow of fuel fromthe associated fuel source and output a flow of fuel. The outputted flowof fuel may be limited to a pressure of approximately eleven inches ofwater column. The normally-closed valve may be in fluid communicationwith the combustion region and in fluid communication with theassociated fuel source. The normally-closed valve may be adapted toshut-off said combustion-powered heater when closed. The oxygendepletion sensor may comprise a burner and a detector. The burner may bein operative engagement with said regulator. The burner may be adaptedto combust fuel in air to produce a flame. The detector may be adaptedto detect a first property of the flame. The detector may be adapted tohold open said normally-closed valve unless the detected first propertyof the flame do not meet predetermined criteria. The flame may beadapted to have the first property not meet the predetermined criteriawhen the air comprises a carbon dioxide amount in the air of more than5000 PPM, or the air comprises a carbon monoxide amount in the air ofmore than 100 PPM, or the air comprises at least 82% by volumenon-oxygen components, or any combination thereof.

BRIEF DESCRIPTION OF THE DRAWINGS

The present subject matter may take physical form in certain parts andarrangement of parts, embodiments of which are described in detail inthis specification and are illustrated in the accompanying drawings.

FIG. 1 is a view of one embodiment of a portable catalytic heaterassembly.

FIG. 2 is another view of one embodiment of a portable catalytic heaterassembly.

DETAILED DESCRIPTION

Reference will be made to the drawings, FIGS. 1-2, wherein the showingsare only for purposes of illustrating certain embodiments of a portablecatalytic heater, and not for purposes of limiting the same. Specificcharacteristics relating to the embodiments disclosed herein are not tobe considered as limiting, unless the claims expressly state otherwise.

Portable heaters 10 may be combustion-powered. A combustion-poweredportable heaters 10 may combust a fuel and an oxidant in a combustionregion 20. A combustion region 20 may comprise, without limitation, acatalytic surface 22 or a burner (not shown).

A catalytic surface 22 is a combustion region 20 adapted so that a fueland an oxidant may react thereupon in catalyzed reaction to yield heatand a combustion product. Without limitation, some portable heaters 10release combustion products to the atmosphere 60.

The material of the catalytic surface 22 may act as a catalyst 24 in acombustion reaction in the combustion region 20. Without limitation, acatalyst 24 in a combustion reaction may change the combustion reactionby speeding up the reaction, slowing down the reaction, lowering theignition energy needed to initiate the combustion reaction, promotingmore complete combustion, promoting cleaner combustion, reducing oreliminating certain combustion products, or increasing operatingefficiency.

Without limitation, some fuels that a portable heater may reactcomprise, methane, ethane, propane, butane, pentane, LP gas, other gasmixtures, and kerosene. Without limitation, some oxidants that aportable heater may react comprise oxygen, gas mixtures comprisingoxygen, nitrous oxide, or mixtures thereof. Without limitation, air is agas mixture comprising oxygen that may be used to provide an oxidant foruse as a combustion reactant.

Use of air, use oxygen from the air, or release of combustion productsto the atmosphere 60 can affect air quality. Without limitation, someportable heaters consume oxygen from the atmosphere 60 as a combustionreactant.

Without limitation, some catalytic surfaces 22 comprise a catalyst 24supported by a substrate 26. In certain embodiments a catalyst 24 maycomprise ruthenium, rhodium, palladium, osmium, iridium, platinum, andmixtures thereof. A substrate 26 may comprise a glass fiber, a porousmetal, a ceramic, or a mixture thereof.

Without limitation, a portable heater 10 may comprise a detector forgauging air quality directly or indirectly. In certain embodiments, adetector for gauging air quality may comprise an oxygen depletion sensor30. In certain embodiments a detector for gauging air quality may detecttemperature.

In certain embodiments, and without limitation, an oxygen depletionsensor 30 comprises a burner 32 adapted to produce a flame and atemperature detector 36. In certain embodiment and without limitations,the temperature detector 36 may comprise a thermocouple, athermoelectric material, a pyrometer, a bimetallic strip, or athermostat. An oxygen depletion sensor 30 may be adapted to detectcertain levels of a gas. In some embodiments, the oxygen depletionsensor 30 may be adapted to detect undesirable levels of a gas.

In certain embodiments, of an oxygen depletion sensor 30, the detector36 is adapted to detect the characteristics of temperature of a flame(not shown) produced by the burner 32. The detector 36 is adapted tohold open a normally-closed valve unless the temperature of the flamedoes not meet a predetermined criteria. In certain embodiments, thedetector 36 produces a current sufficient to hold open a normally-closedvalve 40 as a result of the detection of a flame temperature meeting thepredetermined criteria. In some embodiments a produced currentsufficient to hold open a normally-closed valve 40 may hold open thenormally-closed valve 40 electromagnetically.

In certain embodiments, a flame produced by the burner 32 is adapted tohave a temperature that does not meet the predetermined criteria if theair quality is bad. The quality that makes air bad is subject toengineering judgment. In certain embodiments, and without limitation,the air is bad if the air comprises a carbon dioxide amount in the airof more than 5000 PPM, or the air comprises a carbon monoxide amount inthe air of more than 100 PPM, or the air comprises at least 82% byvolume non-oxygen components, or any combination thereof.

Non-oxygen components refers to those components in the air, including,but not limited to, nitrogen, argon, and carbon dioxide, that are notoxygen. If oxygen is removed from the atmosphere 60, the percentage byvolume of non-oxygen components may increase. If non-oxygen components,such as, without limitation, carbon monoxide, carbon dioxide, ornitrogen oxides, are introduced to the atmosphere 60, the percentage byvolume of non-oxygen components may increase.

Without limitation, an oxygen depletion sensor 30 may detect undesirablelevels of oxygen, carbon monoxide, or carbon dioxide. An atmosphere 60devoid of undesirable levels of a gas may be described as good air or ashaving good air quality. An atmosphere 60 comprising undesirable levelsof a gas may be described as bad air or as having bad air quality.

In certain embodiments, and without limitation, an oxygen depletionsensor 30 may accept air from the atmosphere 60 for use as a reactant inthe combustion of fuel in the burner 32. The composition of theatmosphere 60 can substantially affect performance of the flame producedby the burner 32 during operation. During operations in good air, theflame produced by the burner 32 of an oxygen depletion sensor 30 may beof a first predictable temperature. During operation in bad air, theflame produced by the burner 32 of an oxygen depletion sensor 30 may beof a second predictable temperature. For example, and withoutlimitation, in some embodiments, a flame produced in bad air may belower in temperature, cooler than, a flame produced in good air.

Because of predictable flame temperature differences between a flameproduced from combustion in good air and a flame produced fromcombustion in bad air, a temperature detector 36 may be used to detecttemperature changes related to changes of air quality and, thereby, usedas a predictor of atmospheric conditions in terms of good air versus badair. That is, a temperature detector 36 may be used to discriminatebetween operations within good air and operations within bad air bymeasuring a flame temperature affected by air quality.

In certain embodiments, and without limitation, an oxygen depletionsensor 30 comprises a burner 32 and a thermocouple 38. In certainembodiments, the temperature of the flame produced by the burner 32 inbad air is cooler than a flame produced in good air. In certainembodiments, the thermocouple 38 may be so arranged as to detect thetemperature difference in the flame and to produce an output signalrepresentative of the air quality. In certain embodiments, thethermocouple 38 may be arranged to be proximate to the flame or immersedin the flame or in any arrangement consistent with good engineeringpractice that will discriminate the flame temperature differences ofinterest. In certain embodiments, a flame produced by combustion in goodair quality will produce a output signal from the thermocouple 38consistent with good air quality, and will produce sufficient current tohold open a normally-closed valve. In certain embodiments, a flameproduced by combustion in bad air quality will not produce an outputsignal from the thermocouple 38 consistent with good air quality, andwill not produce sufficient current to hold open a normally-closedvalve. In certain embodiments, a flame produced by combustion in bad airquality will not produce any substantial output signal from thethermocouple 38.

In certain embodiments, failure of the detector 36 to produce an outputsignal consistent with good air may trigger actions to cease heater 10operations. In certain embodiments, actions to cease heater 10operations include shut off or shut down of the heater 10. In certainembodiments, actions to cease heater 10 operations include shut off,closing, or shut down of the heater 10 comprise closing of a valve 40 tointerrupt fuel flow necessary to continuing operation of the heater 10.In certain embodiments, and without limitation, the detector 36 isoperationally engaged with and holds open a normally-closed valve 40unless the detector fails to detect a temperature consistent withoperation of the burner 32 in good air. In some embodiments, closing ofsaid valve 40 terminates a flow of fuel necessary to the continuedoperation of heater 10 and, thereby, stops heater 10 operation.

In the non-limiting embodiment shown in FIGS. 1 and 2 a portablecatalytic heater 10 is adapted to be supplied by an associated fuelsource (not shown). Heater 10 may comprise a fuel source connection 12.Without limitation, a fuel source connection 12 may comprise afemale-threaded region (not shown) adapted for connection to anassociated male-threaded fuel source (not shown). Without limitation, afuel source connection 12 may be adapted for connection to an associatedpropane fuel tank or bottle.

A portable catalytic heater 10 may comprise a combustion region 20comprising a catalytic surface 22. When the portable catalytic heater 10is in operation, the combustion region 20 may receive fuel from anassociated fuel source (not shown) through a valve 40. In operation, thecombustion region 20 may receive air (not shown) from the atmosphere 60and may react the air and the fuel upon catalytic surface 26 to yieldheat and a combustion product. A combustion product may be released tothe atmosphere 60.

Heater 10 may, optionally, comprise a regulator 14. When the portablecatalytic heater 10 is in operation, an optional regulator 14 mayreceive fuel from an associated fuel source 40. The regulator 14 maythroughput fuel at a regulated pressure. In some embodiments, withoutlimitation, a heater 10 may comprise a regulator 14 to regulate thepressure of fuel directed to an oxygen depletion sensor 30, a regulator14 to regulate the pressure of fuel directed to a combustion region 20,or both. In certain embodiments, the fuel directed to an oxygendepletion sensor 30 or the fuel directed to a combustion region 20 arenot regulated. Without limitation, in certain embodiments, the regulatedpressure may be approximately eleven inches of water column.

In operation, burner 32 may burn the fuel with air from the atmosphere60, may produce a flame (not shown), and may produce combustion products(not shown). A combustion product may be released to the atmosphere 60.The flame produced by burner 32 may interact with thermocouple 38 in amanner that depends upon the quality of the air. If the air is good,then flame may heat thermocouple 38 sufficiently to produce an outputsignal consistent with good air quality. If the air is bad, then theflame may not heat thermocouple 38 sufficiently to produce an outputsignal consistent with good air quality. If the thermocouple 38 is notheated sufficiently to produce an output signal consistent with good airquality, then valve 40 will close stopping fuel supply to combustionregion 20 and thereby shutting down the portable catalytic heater 10.

While the portable catalytic heater has been described above inconnection with the certain embodiments, it is to be understood thatother embodiments may be used or modifications and additions may be madeto the described embodiments for performing the same function of theportable catalytic heater without deviating therefrom. Further, theportable catalytic heater may include embodiments disclosed but notdescribed in exacting detail. Further, all embodiments disclosed are notnecessarily in the alternative, as various embodiments may be combinedto provide the desired characteristics. Variations can be made by onehaving ordinary skill in the art without departing from the spirit andscope of the portable catalytic heater. Therefore, the portablecatalytic heater should not be limited to any single embodiment, butrather construed in breadth and scope in accordance with the recitationof the attached claims.

What is claimed is:
 1. A portable heating device comprising: acombustion-powered heater, supplied by an associated fuel source, andcomprising a combustion region comprising a catalytic surface; aregulator adapted for fluid communication with the associated fuelsource; and an oxygen depletion sensor (ODS), configured to selectivelyrender the combustion-powered heater non-functional when a non-desiredatmosphere is detected, said ODS comprising a burner in fluidcommunication with said regulator, said burner adapted to combust fuelfrom said regulator with air to produce an ODS flame, and a temperaturedetector, adapted to detect the temperature of said ODS flame whereinsaid temperature of said ODS flame is indicative of a desired atmosphereand said non-desired atmosphere; wherein said ODS flame is adapted tohave a temperature indicative of the non-desired atmosphere when theatmosphere comprises one or more of: a carbon dioxide amount of morethan 5000 PPM; a carbon monoxide amount of more than 100 PPM; or atleast 82% by volume non-oxygen components.
 2. The heating device ofclaim 1, wherein said combustion-powered heater is adapted to consumeoxygen from the atmosphere as a combustion reactant or is adapted torelease a combustion product into the atmosphere.
 3. The heating deviceof claim 2, wherein said regulator is adapted to output a flow of fuelfrom the associated fuel source to the ODS burner a pressure ofapproximately eleven inches of water column.
 4. The heating device ofclaim 1, wherein said catalytic surface comprises a catalyst and asubstrate.
 5. The heating device of claim 1, wherein saidcombustion-powered heater further comprises a valve in fluidcommunication with said combustion region and in fluid communicationwith said associated fuel source.
 6. The heating device of claim 5,wherein said ODS is configured to close said valve upon detection oftemperature of said ODS flame indicative of the non-desired atmosphere.7. The heating device of claim 4, wherein said catalyst comprisesruthenium, rhodium, palladium, osmium, iridium, platinum, or mixturesthereof.
 8. The heating device of claim 4, wherein said substratecomprises a glass fiber, a porous metal, a ceramic, or a mixturethereof.
 9. The heating device of claim 1, wherein said associated fuelsource comprises propane.
 10. A portable combustion-powered heatersupplied by an associated fuel source, said combustion-powered heatercomprising: a combustion region comprising a catalytic surface; aregulator operationally engaged with the associated fuel source; avalve; and an oxygen depletion sensor (ODS), operationally engaged withsaid regulator, and configured to detect a non-desired atmosphere, saidODS comprising, a burner in operative engagement with said regulator,said burner adapted to combust fuel in air to produce an ODS flame, anda detector, said detector being adapted to detect a first property ofthe ODS flame, wherein the first property of the ODS flame is an ODSflame temperature indicative of a a desired atmosphere and saidnon-desired atmosphere; wherein first property is indicative of saidnon-desired atmosphere when the atmosphere comprises one or more of: acarbon dioxide amount of more than 5000 PPM; a carbon monoxide amount ofmore than 100 PPM; or at least 82% by volume non-oxygen components. 11.The combustion-powered heater of claim 10, wherein saidcombustion-powered heater consumes oxygen from the atmosphere as acombustion reactant, or releases a combustion product into theatmosphere, or both.
 12. The combustion-powered heater of claim 10,wherein said catalytic surface comprises a catalyst and a substrate andwherein: said catalyst comprises ruthenium, rhodium, palladium, osmium,iridium, platinum, or mixtures thereof; and said substrate comprises aglass fiber, a porous metal, a ceramic, or a mixture thereof.
 13. Thecombustion-powered heater of claim 10, wherein said valve is adapted toshut-off said combustion-powered heater when closed.
 14. Thecombustion-powered heater of claim 10, wherein said valve is anormally-closed valve.
 15. The combustion-powered heater of claim 14,wherein said ODS is adapted to hold open said normally-closed valveunless the non-desired atmosphere is detected.
 16. Thecombustion-powered heater of claim 10, wherein said regulator is adaptedto output a flow of fuel from the associated fuel source to the ODSburner a pressure of approximately eleven inches of water column. 17.The combustion-powered heater of claim 10, wherein said fuel is propane.18. A portable heating device comprising: a combustion-powered heatersupplied by an associated fuel source, wherein said fuel sourcecomprises propane, and wherein said combustion-powered heater comprisesa combustion region comprising a catalytic surface comprising a catalystand a substrate, and wherein: said catalyst comprising ruthenium,rhodium, palladium, osmium, iridium, platinum, or mixtures thereof, andsaid substrate comprising a glass fiber, a porous metal, a ceramic, or amixture thereof; said combustion-powered heater is configured to performone or more of: consume oxygen from the atmosphere as a combustionreactant or release a combustion product into the atmosphere; aregulator operationally engaged with the associated fuel source, whereinsaid regulator is configured to output a flow of fuel from theassociated fuel source to an ODS burner a pressure of approximatelyeleven inches of water column. a normally-closed valve, wherein saidvalve is in fluid communication with said combustion region and in fluidcommunication with said associated fuel source, and wherein said valveis configured to shut-off said combustion-powered heater when closed;and an oxygen depletion sensor (ODS), configured to hold open saidnormally-closed valve unless a depleted level of oxygen is detected,said ODS comprising, said ODS burner in operative engagement with saidregulator, wherein said ODS burner is configured to combust fuel in airto produce an ODS flame a detector, wherein said detector is configuredto detect a first property of the ODS flame and wherein the firstproperty of the ODS flame is indicative of a depleted oxygen contentwhen the atmosphere comprises a carbon dioxide amount of more than 5000PPM, or the atmosphere comprises a carbon monoxide amount of more than100 PPM, or the atmosphere comprises at least 82% by volume non-oxygencomponents, or any combination thereof.
 19. The heating device of claim18 wherein, said first property of the ODS flame is temperature; andsaid depleted level of oxygen is indicated by a temperature operatingoutside of an acceptable temperature operating range.